I have shipped with Purolator. You need to set up an account (not a big deal), declare it is as powder and ship by ground transportation.
It was neither particularly hard nor particularly cheap.
In my experience, costs really go up if the person is not in a major centre. If they live remotely, sometimes it is better to send it to a more major centre, as long as there is someone available to accept the delivery and then the buyer can retrieve it at their convenience.
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